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You can find them in Pokeballs lying in random places or, you can go to this old man's house in Voilet City acnd give him apricots. He'll make the apricots into Pokeballs but, you have to wait one day to get them.

No you can't. Master Balls are not the type to be lying around or fabricated by an old man.

After you have obtained the first 8 badges, go to Professor Elm in New Bark Town to get your first Master Ball.

TO GET MORE MASTER BALLS you have to Pokemon Lottery in Goldenrod City Radio Tower and talk to the girl at the center of the desk on the ground floor. If all 5 of the lottery numbers match one of your PoKéMoN's ID numbers perfectly, you will win a Master Ball. You can try this as many times as you like, but only once per day.

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14y ago

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