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To get rid of the pesky psyduck there are a few steps that need to be taken.

1. defeat the leader Crash Wake at the Pastoria gym

2. talk to the team galactic member stationed near the entrance to the safari zone area, which is also found in Pastoria city.

3. the galactic member will leave and you must follow him and talk to him again(you will see which direction he leaves so it will be obvious to you which way to go)

4. eventually he will decide to battle you with a glameow which is easily defeatable.

5. follow the direction he leaves after the battle is won and you will come across Cynthia at the entrance to a lake ( the name of which escapes me). She will provide you with the medicine required to make the psyduck leave.

Hope I have Helped

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