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Which one? There are three Trios.

Tao Trio:

Reshiram - Captured during the storyline in Pokemon Black

Zekrom - Captured during the storyline in Pokemon White

Kyurem - Captured in the Giant Chasm north of Route 13

Kami Trio:

Thundurus - In Pokemon White, after obtaining all 8 badges, go to route 7. Walk up to the house where the woman was cooking and she will come out and talk to you. After that, Thundurus is wandering the region, in the south during the morning and north in the evening. If you enter a Route and a giant thunderstorm is raging, go in the wild grass and there is a good chance he will show up.

Tornadus - In Pokemon Black, same way as Thundurus.

Landolus - Get Thundurus and Tornadus on the same cartridge and go to the Abundant Shrine, north of Route 14 to find Landolus.

Musketeer Trio:

Cobalion - After you get surf, surf east of Mistveil to the Mistveil cave. He will be on the top floor.

Virizion - Go to pinwheel forest and he will be there(only after you have confronted Cobalion)

Terrakion - Go to the Pokemon league. Go south and back into the top cave of victory road. Take the top left stairway and follow that path to find Terrakion (only after confronting Cobalion.)

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13y ago

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