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You'll need to obtain the Mega Stone called Gardevoirite, which can be obtained from Diantha's Ralts when she trades it to you (X and Y) or break the rocks between Rusturf Tunnel and Verdanturf Town, then go into the house where the girl lives in Verdanturf Town. (Omega Ruby and Alpha Sapphire) Attach the Gardevoirite to your Gardevoir, then go into battle. A new button will appear called "Mega Evolve". It'll Mega Evolve Gardevoir before it uses its move on its turn.

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Related Questions

Is Gardevoir strong?

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How do you get Gardevoir in Pokemon HeartGold?

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