What is Angelina Jolie's sexual orientation?

Answer 1

According to numerous media reports, Angelina Jolie is openly Bisexual.
She is bisexual
Yes. She hasn't talked about it since the late 90's/early 2000's though. She was in a film called Hackers, with actress/model Jenny Shimizu, of whom she had relations with. Since, she has not been involved with a woman, only men.
Yes, Angelina Jolie openly identifies as bisexual, and has had publicized relationships with both men and women, including her co-stars Brad Pitt and Jenny Shimizu.

Answer 2

She is a Bisexual ;)