You're probably thinking of Marathon Man , where the character played by Hoffman is being tortured by an evil dentist in order to get information.
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Brad Pitt and Dustin Hoffman appeared together in Sleepers.
'Rainman'. Dustin Hoffman plays the character of Raymond, who is an autistic savant.
It is the movie, The Graduate, likely the film Dustin Hoffman is most known for.
Rain Man
Marathon Man