Reactions that increase the randomness. Reactions that have more moles of gas on the product side than the reactant side increase entropy. Also reactions that have a positive change in spontaneity and a negative enthalpy.
Increase in entropy.
An irreversible process occurs whenever there is an increase in entropy. Entropy can be thought of as a measure of "wasted" energy, that is, energy that cannot be converted to useful work. Therefore any process which results in an increase in entropy wastes some portion of energy that cannot be recovered, and so the process is irreversible.
Books in the return bin are in more disorder or disarray than the books organized on library shelves. An increase in disorder is an increase in entropy.
"This is a difficult question to answer exactly since (1) potential energy is not something that is directly measured - it can only be deduced from the heats produced or absorbed in a transformation, and (2) the heat produced or absorbed (enthalpy) in a chemical transformation vary from substance to substance. In general, we expect that when chemical bonds are formed, energy is released - imagine the individual atoms as having energy and have to be slowed down in order that chemical bonds can form. Alternatively, and more accurately, when two atoms spontaneously form a chemical bond it must mean that the entropy of this system has increased, since two separate atoms have more disorganization (entropy) then one complete molecule, then in order for the process to be spontaneous (entropy increases), there must be some heat released. The problem now is relating heat to potential energy. I would rather you relate this to internal energy rather than potential energy (which is not quite directly applicable to chemical systems). If we think of internal energy, we know, by definition, that internal energy is a function of the heat and work that goes in and out of the system. Since most chemical transformations do not involve work, then internal energy is mostly a function of the heat that enters or leaves the system. Thus, when a chemical bond is formed spontaneously, heat leaves the system, the internal energy of the system goes down. You may then think of internal energy as a kind of potential energy and say that because the system is less energetic (since heat left the system) that it must now have a lower potential energy."
This is called entropy.
Chemical reactions that release energy often occur spontaneously because they lead to a decrease in the overall energy of the system. Exothermic reactions, which release heat energy, are usually spontaneous because they increase the randomness or entropy of the system, following the second law of thermodynamics. This decrease in energy and increase in entropy drive the reaction to proceed without the need for external energy input.
In a chemical system, exothermic reactions release heat energy, while entropy changes refer to the disorder or randomness of molecules. Exothermic reactions typically lead to an increase in entropy, as the released heat energy can increase the movement and randomness of molecules in the system.
When energy is transformed, entropy can either increase or decrease. For example, in many energy transformations, such as combustion or chemical reactions, entropy tends to increase due to the dispersal of energy. However, in some processes, such as certain phase changes, entropy can decrease.
Reactions that increase the moles of gas will increase in entropy.
Favorable chemical reactions are those that release energy, produce a decrease in entropy, or result in the formation of more stable products. These reactions typically proceed in the direction of equilibrium and are thermodynamically spontaneous. Examples include combustion reactions and exothermic reactions.
A gas typically increases the entropy much more than the increase in moles.
Negative entropy is a process or chemical reaction proceeds spontaneously in the forward direction.Positive entropy is a process proceeds spontaneously in reverse.
Chemical reactions occur spontaneously when the free energy of the product is less than the free energy of the reactants. Free energy is a combination of thermal energy (heat) and entropy. If thermal energy is absorbed during a reaction, there must be an exceptionally large increase in entropy to give a net reduction in free energy.
The difference can be clarified by entropy (the second rule of thermodynamics).The reaction is more spontaneous with higher entropy, for the reactions that occur spontaneously the entropy is higher than for the ones that do not.
Entropy increases. In a reaction comprised of sub-reactions, some sub-reactions may show a decrease in entropy but the entire reaction will show an increase of entropy. As an example, the formation of sugar molecules by living organisms is a process that shows decrease in entropy at the expense of the loss of entropy by the sun.
Exothermic reactions release heat energy to the surroundings, increasing their entropy by dispersing the energy. This leads to greater disorder and randomness in the surroundings, contributing to an overall increase in entropy.
Yes, the second law of thermodynamics states that in any spontaneous process, the overall entropy of a closed system will increase over time. This means that in physical and chemical systems, energy tends to disperse and distribute randomly, leading to greater disorder (entropy) in the system.