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H2O would be solid (ice) at 32ºF at standard pressure. Standard pressure is the atmospheric pressure at sea level which would be 1 ATM (atmosphere) or 14.5 psi (pounds per square inch). If the pressure was reduced, such as in a vacuum, water could remain liquid far below its standard freezing point. The same goes for increasing the pressure. You could generate solid water well above the melting point by increasing the pressure in a vessel.

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