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This depends on the specific characteristics of the rock in question.

Sedimentary rocks such as sandstones may be highly porous (i.e. they have a large number of voids within them known as pore spaces) and as such may be very effective at storing water. Other sandstones may have a silica or calcite cement matrix that has formed around the clasts, greatly reducing porosity and meaning they are poor at storing water.

Igneous rocks such as granite or basalt are generally very poor at storing water as they are formed of tightly interlocking crystals and so have extremely low porosities.

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