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You would use the equation ΔQ = mcΔT, where ΔQ means change in energy (or energy required in this case), m is mass of water, c is specific heat capacity, and ΔT change in temperature. Water's specific heat capacity (energy needed to raise 1kg by 1 degree K or C) is 4200J Kg-1 K-1, so, if we put your numbers in: Q = 40kg x 4200J Kg-1 K-1 x 20°C (20 degress kelvin)

Q = 3360000J, or, 3360KJ, or 3.36MJ of energy. This is assuming that the temperature change does not get the water to boil, as then you have to factor in the latent heat of vapourisation...

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