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Zinc Oxide is originally a white powder. When heated up, it turns yellow but does not decompose and when it is removed from the heat it gradually goes back to its original white colour. If you heat it strongly enough to very high tempereatures it will sublime without apparent decomposition.

The reason for the yellow colour is that a minute amount of oxyegen evaporates from the lattice (70 ppm) the small number of zinc atoms produce lattice defects that give rise to the colour. Doping zinc oxide with minute traces of zinc will give a range of colours, yellow, green brown and red.

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