The Piper diagram not only shows graphically the nature of a given water sample, but also dictates the relationship to other samples. For example, by classifying samples on the Piper diagram, we can identify geologic units with chemically similar water, and define the evolution in water chemistry along the flow path. In Piper diagrams the concentrations are expressed as meq/L.
To construct the Piper diagram, the relative abundance of cations with the %meq/L of Na++K+, Ca2+, and Mg2+ is first plotted on the cation triangle. The relative abundance of Cl-, SO42-, and HCO3-+CO32- is then plotted on the anion triangle. The two data points on the cation and anion triangles are then combined into the quadrilateral field that shows the overall chemical property of the water sample
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purposes of the piper diagram
the number of cations and antions.
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Water analyses plotted on a Piper diagram. Cation percentages in meq L-1 plotted on the left triangle, and anion percentages in meq L-1 plotted on the right triangle.
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A Piper diagram is a graphical representation used to display the chemical composition of water samples, facilitating the comparison of water quality data. It consists of three main components: a central diamond shape that shows the relative proportions of cations and anions, and two triangular plots on the sides that detail the individual cation and anion concentrations. The position of a sample within the diagram indicates its water type and helps identify relationships between different samples. By analyzing the patterns and clustering of points, one can infer geochemical processes and influences on water quality.