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The atmosphere should have the greatest impact on the other Earth spheres if the atmosphere were catastrophically damaged. If the atmosphere turned poisonous or something, most living organisms will die. So, this damaged air will affect the biosphere. So, with the biosphere damaged from the atmosphere, it will affect the lithosphere. The affected lithosphere would obviously ruin the rocks and minerals on the Earth. With both lithosphere and atmosphere damaged, the hydrosphere would become damaged also because of the poisonous air and a non-healthy Earth.

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Q: Which of the Earth's spheres would have the greatest impact on the others if it were catastrophically damaged?
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