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pH is a function of the concentration of hydronium ions in a water solution and theoretically can take any number, not just the traditional 1-14 range. However there are physical limits to how much of this substance can be present in a solution without precipitating and this establishes the lower limit of pH. At the other end of the scale pH can be determined mathematically from the concentration of hydroxide ions, but this too is limited to a point, setting the upper limit for pH. These limits take the allowable pH range down to about -5 and up to perhaps 20.

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