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Capillaries are tiny blood vessels which allow only very few blood cells to get through at a time. When blood cells enter the capillaries, the oxygen and nutrients which are stored in hemoglobin in the blood diffuse into the body. The exhausted blood cells then enter back into larger vessels to join the bloodstream once again. The cycle goes something like this:

Heart pumps blood --> blood cells pick up oxygen in alveoli in the lungs --> the heart pumps fresh blood through arteries to the body --> the arteries narrow down into capillaries in which aforementioned diffusion takes place --> capillaries grow back into veins which carry blood back to the heart and, ultimately, the lungs --> the process repeats.

Many people confuse veins with arteries. A vein is defined as a blood vessel which carried blood to the heart. MOST veins carry de-oxygenated blood; but not all. Once the depleted blood has passed through the heart, it goes to the lungs where it then goes back to the heart. The only vein which carries oxygenated blood in the one connecting the lungs and the heart. The same is inversely true for arteries; arteries carry blood away from the heart. MOST of this blood is full of oxygen; except for the blood in the artery going FROM the heart TO the lungs. This can be more easily understood by examining a diagram which I cannot attach with this answer.

You may be asking "Why does it look like my blood vessels are blue when I bleed red?" The blue vessels you are seeing are oxygen-depleted veins. When the protein, hemoglobin, is full of oxygen, it colors the blood cell red. So, the arteries in your body are red, because they are full of oxygen. As soon as your skin is broken, your blood cells are exposed to oxygen, thus causing them to instantly turn red. This is not perceptible to the human eye.

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