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The most abundant plasma electrolytes are sodium, potassium, calcium, bicarbonate, magnesium, and chloride. Sodium is the primary cation in extracellular fluid, playing a crucial role in maintaining fluid balance and regulating blood pressure. Potassium is the main intracellular cation, essential for cellular function and muscle contraction. These electrolytes are vital for various physiological processes, including nerve conduction and muscle function.

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