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Very indirect.

kcals measures the amount of energy in food. And energy is transported through the blood in the form of glucose (sugar).

But the amount of glucose in the blood is determined not just by how much food you eat, but by how quickly it's changed into glucose, how much of it is absorbed into the blood and how fast, and how quickly that glucose is accepted into the cells (which depends on insulin levels).

So you can't really establish a direct relationship since there are too many other major factors.

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