aromatic alcohols undergo resonance which stabilizes the conjugate base, in aliphatic alcohols +I effect of alkyl group increase the -ve charge in the conjugate base thus make it unstable
Aromatic acids are generally stronger than aliphatic acids due to the resonance stabilization provided by the delocalization of electrons in the aromatic ring. This makes the aromatic acids more stable when releasing a proton, resulting in a stronger acid.
Phenol is more acidic than aliphatic alcohols and water because the benzene ring stabilizes the phenoxide ion formed upon deprotonation, making it more favorable to lose a proton. This stabilization is due to resonance delocalization of the negative charge in the phenoxide ion. In aliphatic alcohols and water, there is no such resonance stabilization, resulting in weaker acidity.
yes
Aromatic aldehydes contain an aromatic ring in their structure, while aliphatic aldehydes have a straight or branched carbon chain. Aromatic aldehydes typically have a stronger smell compared to aliphatic aldehydes due to their benzene ring. Aromatic aldehydes are commonly found in natural sources like plants, while aliphatic aldehydes are more often associated with industrial processes.
Aliphatic amines are stronger bases than aromatic amines because the lone pair on the nitrogen atom in aliphatic amines is more available for donation due to the absence of resonance effects that stabilize the lone pair in aromatic amines. This makes aliphatic amines more likely to accept protons and act as bases.
Aliphatic hydrocarbons have straight or branched carbon chains, while aromatic hydrocarbons contain a benzene ring or other aromatic rings in their structure. Aliphatic hydrocarbons are typically less stable and more reactive than aromatic hydrocarbons due to differences in bond types and energy. Aromatic hydrocarbons exhibit unique properties such as resonance stabilization and are often used as precursors for various organic compounds.
aromatic diazo compounds are stabilize by resonance where as in alifati it is not found
Aliphatic compounds could be straight chain structures [Acyclic] like alkanes or cyclic structures, like cycloalkanes. Aliphatic compounds are hydrocarbon chains - strings of carbon atoms connected to each other with hydrogen atoms hanging off the sides of the chain. one exception for the definition of aliphatic side chain is Proline which also has aliphatic side chain but the its side chain is bonded to both carbon and nitrogen. Aromatic compounds have benzene ring (older notion). Aromatic compounds are those which follow Huckel's rule. (4n + 2pi) rule. They have the general formula: CnH2n-6 [where n is equal to or greater than 6] Aromatic compounds are rings - so take the chain and connect the two ends together to form a continuous loop.
Typically aromatic groups attached to functional groups increase the reaction over that of an aliphatic groups. Aromatic aldehydes (e.g. benzaldehyde, C6H5.CHO), are also known which undergo a number of chemical reaction which do nor occur for aliphatic aldehydes and which are unique to aromatic aldehydes.
Yes, aromatic compounds are generally more acidic compared to other types of compounds due to the presence of a stabilizing resonance structure in their conjugate bases.
The electron withdrawing ability of the aromatic ring and its subsequent ability to delocalize the charge around the pi electron cloud of the ring, make the phenol Hydrogen fairly acidic. This reacts well with the alkaline sodium hydroxide. The H on the alcohol is not acidic.
Aliphatic amines do not typically give coupling reactions due to their limited aromatic character, which is necessary for coupling reactions to occur effectively. Aromatic amines are more likely to undergo coupling reactions because they possess a delocalized pi system that stabilizes the intermediates formed during the coupling process.