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There are two ways to interpret this question. One is, what is the herbal chemical equivalent, and one, more general, what herbs can help, relax, tranqulize like Valium.

First off a minor tranquilizer relaxes by relaxing the muscles. In other words it helps ease up tense muscles. That being said, there are different categories of herbals that can relax. There are calmatives. These botanical are calming hence the name. There are nervines. These strengthen the nerves. Another category is antispasmodic. While these arn't exactly relaxing herbs they help calm cramping. In this way they help with stomach distress and thereby they are helpful in dealing with physical stress. Finally there are relaxants. Medicinal plants that are most helpful in making people feel relaxed. Scullcap, Wood Betony, Passionflower and Valarian are excellent relaxing herbs for most people.

Some herbs, including chamomile, sage, lemon balm, and holy basil, are also relaxing, but have markedly milder or weaker effects than valium, and accordingly, are much safer.

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