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That is a mighty big question no one realy knows they have found it 4-5000 years ago through archialogy and was even used by the great Doc. Galin in treatment of his pacients in Rome. But through out history of humans at least when we left the neolithic era and forged into agriculture it has been around perhaps longer, predating recorded history so that question is like asking who invented fire.

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16y ago

What else can I help you with?