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Robert La Salle's major accomplishment was his exploration of the Mississippi River and its surrounding regions, which he claimed for France. In 1682, he successfully navigated the river to its mouth at the Gulf of Mexico, naming the vast territory "Louisiana" in honor of King Louis XIV. This expedition significantly expanded French territorial claims in North America and contributed to the exploration of the continent. La Salle's efforts laid the groundwork for future French colonization and trade in the region.

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