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The Peace of Nicias was broken by the Sicilian Expedition, which was initiated by Athens in 415 BCE. This military campaign aimed to expand Athenian influence and control over Sicily, but it ultimately resulted in a disastrous defeat for Athens. The aggressive actions of Athens, particularly the decision to invade Sicily despite the ongoing peace, marked a significant turning point in the Peloponnesian War and escalated hostilities with Sparta and its allies.

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