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The Spanish.

In 1524, a band of ruthless Spanish conquistadores under the command of Pedro de Alvarado moved into present-day Guatemala. The Mayan Empire had deteriorated some centuries before, but survived as a number of small kingdoms, the strongest of which was the K'iche, whose home was in what is now central Guatemala. The K'iche rallied around leader Tecún Umán and met Alvarado in battle, but were defeated, ending forever any hope of large-scale native resistance in the area.

I got this info from About.com =] so to answer your question its Pedro de Alvarado.

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