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That depends on where you are and what kind of explosives you make. The ATF redefined the word 'explosives" last year to include several products that were not previously considered explosives. In many places you can make your own black powder, rocket propellants and fuse. Some more powerful "explosives" can be made in very small quantities for use in fireworks, but there are restrictions on the storage of explosives. For more detailed and up to date rules, go to atf.gov.

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