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Dobereiner's classification, which grouped elements into triads based on similar properties, had several limitations. It only encompassed a small number of elements, primarily focusing on the known elements at the time, which were insufficient to represent the entire Periodic Table. Additionally, not all elements could be neatly categorized into triads, and it failed to account for the periodicity of properties across larger groups of elements. This classification system was ultimately superseded by more comprehensive frameworks, like Mendeleev's periodic table.

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