Either steady or trusty.
A potential word that means "ascend" and rhymes with "rhyme" is "climb."
Reliable.
join
board or boards
The word reliable has four syllables. Re-li-a-ble.
The word that means and rhymes with cloak is "joke."
The word that means kneel and rhymes with melt is "knelt."
The word "afraid" slant rhymes with the word "away" but means scared.
The word that rhymes with day and means sky is "gray."
The word that rhymes with angel and means free is "mangel."
The word that rhymes with "creed" and means the opposite of follow is "lead".
One word that rhymes with 'it' and means resist is 'pit'. In this instance the word 'pit' means to set in direct opposition.
The word "lean" fits your criteria as it means cool and rhymes with green.
The word that means a little wet and rhymes with "boist" is "moist."
The word that means to begin and rhymes with "part" is "start."
The answer is weep. Weep rhymes with leap, and means to cry.
A word that rhymes with "now" and means "sad" is "sallow."