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There are several chemicals mentioned in Breaking Bad. Crystal meth (the drug Walter and Jesse cook), methylamine (the drum of organic ammonia derivative that Walter and Jesse steal in season one), hydrofluoric acid (the acid Walter and Jesse use to make "pink smoothies" of Krazy-8's and Emilio Koyam's bodies).

It is possible, I suppose, that you could be referring to the elements shown in the title: Br in "Breaking" is Bromine, number 35 on the Periodic Table, and Ba in "Bad" is Barium, number 56 on the periodic table.

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