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yes you can. I've tried to catch mesprit but instead I caught Uxie in the Aucurity cavern and Azelf in valor lake front where team galactic was. It's really easy just decrease the HP as low as possible and I used a dusk ball. when the ball glows yellow rub the screen with the pen in the ds as hard (but not to hard) and as fast as possible. If you have more Pokemon questions just ask me and next time give me you're code so I can register you. Theres you're answer!

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Q: Can you catch Uxie and Azelf without catching Mesperit?
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When do you use a dusk ball to catch azelf?

when he is insanely low - less than 1/4 cm of hpAt any time--the catching of Azelf comes mostly down to luck. For example, I currently have Azelf down to one HP and asleep; however, I have used fifty five dusk balls and still he continues to break free. This is because Azelf has a 3% Catch Rate out of a hundred, which is low enough to send people to mental institutions. It is highly unlikely lowering its HP amounts to making up for the remaining 97%. For all intents and purposes, catching Azelf is more up to chance than timing or HP lowering. That's not to say don't do it; just take the advice with a grain of salt.