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Alice was a "pure heart" because she had became entangled with the Queen of Hearts and this analogy can go even further than one thinks. Alice was a young girl who was not effected by the imaginary world yet and when she, in fact, falls deep into this strange and "new" world, she experiences numerous life-changing events. One of which changes her pure heart into a mature and understanding heart instead.

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Q: How Alice in Wonderland was pure heart?
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