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When the p and n are joined together they form what is called the "p-n junction." When they are joined some of the electrons from the n side of the junction move to the p side. When certain kinds of light hit the photovoltaic cell, some of the electrons move from the p side to the n side. In both cases the electrons have gained energy and can pass through a circuit--this creates an electrical current.

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Q: How a photocell generates electricity?
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