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Besides the Master Ball there is no way to attain 100 percent rate outside of cheating. To get the best catch rate the Pokemon needs to be at 1 HP and asleep. Then the type of Poke Ball further increases the catch rate for example using Dusk Balls while in caves. In general Ultra Balls are the best Poke Ball due to price and good catch rate. Though some Poke Balls like the Dusk Ball have better catch rate than the Ultra Ball if you meet the right conditions.

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10y ago

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