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You'll need to increase Munchlax's Happiness to max before you could evolve it. Although, it is a rare case for a Pokemon to not evolve without holding a Everstone till level 100, (Excluding those needing to trade, use of a stone, etc.) I recommend you take it to battle again after you are confident that its Happiness is at max and win the battle. Make sure it isn't holding an Everstone as well.

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Q: How do you evolve munchlax when he is a lv 100?
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