She saw him with his mask off close to the end in "Spider-Man 2".
Spiderman
If you are talking about Spiderman (Peter Parker) then it was Tobey Maguire.
Yes, in the first Spiderman, Peter Parker has Thanksgiving (?) dinner with the Green Goblin, Harry's dad, and Harry, who turns out to be a sort of second Green Goblin in the third Spiderman, but he doesn't know it at the time.
In "Spider-Man 2"- Peter Parker takes his mask off to get through to Doc Ock, and that is when Mary-Jane Watson sees his real face.
Peter Parker is the name of a fictitious character who plays the role of superhero, Spiderman. The part of Peter Parker has been played by several actors including Drake Bell and more recently, Andrew Garfield.
Peter Parker.
Peter Parker, a.k.a Spiderman.
Peter Parker is the character in the that is spider man. Peter Parker/spiderman is played by Toby McQuire, and no he is not dead
Spiderman
25.
Toby Mcguire plays the role of Peter Parker in Spiderman.
Spiderman's secret identity is Peter Parker. The actor for Spiderman is Tobey Maguire.
He took pictures of spiderman and delivered pizza
Spider-Man (Peter Parker).
Spider-Man and Peter Parker will be played by Andrew Garfield.
He is the main character in Marvel Comic's Spiderman. On a class trip, Peter Parker gets bitten by a radioactive spider and that spider transforms him into the superhero known as Spiderman. Peter Parker's parents were killed when he was an infant and he went to live with his Aunt May and Uncle Ben. Peter Parker's Uncle Ben was killed by an intruder.
Peter Parker was Mary-Jane Watson's husband as she did take the name Mary-Jane Parker