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Not only on Motorola Portable radio, but in all radio communications:

Frequency is number of cycles (full change circles) per second. When radio device operates on some frequency it requires band of adjacent frequencies to be able to transmit modulation (information) too. To avoid mixing, next transmitter must take some "distance" (higher or lower frequency) far enough from frequency of the first one. According to regulations basic frequencies are "named". Channel number is the name of its frequency given by communication regulations.

For example, TV UHF channel 21 takes all frequencies from 512 to 518 MHz (megahertz), channel 22 from 518 to 524 MHz, and so on...

CB Radio channels 21 and 22 occupy frequencies from CB band, not from TV band. Tables of channel frequencies within various bands can be easily found by search engines.

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