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First Answer:

I don't remember what episode it was it was one of the early ones. But he gets bitten by a hollow (they are basically demons of the underworld) and when you are devoured or bitten you get possesed. When that happens the hollow posses him but he ends up fighting out of it. In later episodes Ichigo uses the power of the hollow inside him to fight. You have to see the anime to find out.

Second Answer:

If we're talking about when Ichigo becomes possessed by his hollow form when he doesn't know how to control it, I think it's episode 60, when he fights Byakuya Kuchki.

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13y ago

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