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Spider-Man doesn't have a 'main villain' and, like most superheroes, fought a variety of characters. His main villains would likely be Dr. Octopus, Green Goblin, and Venom. (The majority of his villains follow an animal theme: Scorpion, Dr. Octopus, Rhino, Vulture, Venom/Carnage (spider), etc.)

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13y ago

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