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In the field of spectroscopy absorption a peak means the wavelength of radiation where a sample absorbs. Different molecules absorb radiation of different wavelengths. An absorption spectrum will show a number of absorption bands, each one corresponding to structural groups within the molecule. Each band is represented by peak if you plot absorbance vs wavelength. By knowing which structural groups correspond to which peaks, you can often identify a compound by it's spectrum. For many molecules, the spectrum has been characterized, and you can use the spectrum to determine the purity, concentration, or other properties of the molecule by looking at the position and intensity of the peaks in the absorption spectrum.

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