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Radio waves are electromagnetic waves, which consists of electric & magnetic fields. When they hit matter they exert forces on the charges of the atoms that make up the matter. Radio waves are usually pretty weak so when they hit most materials not much happens because the atomic charges are pretty firmly in place. However, in metals some of the atomic electrons are not firmly in place and will be easily moved by a radio wave. This is why antennas work. The radio wave causes currents in the antenna which can be sent to a circuit which can convert the currents into the information that was sent by the radio wave (TV & Radio), if it was carrying information.

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