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It possibly could. Ethanol (one of two types of rubbing alcohol, and the kind of alcohol that is used in beverages) is known to diffuse through skin, both inward, into the body, and outward, away from the body. That said, the kinetics of alcohol transport across the skin is not completely understood, and is the subject of ongoing research. Here is a recent (2005) paper on the subject from the Japan Journal of Physiology (in english): http://jap.physiology.org/cgi/reprint/100/2/649.pdf

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Q: Can alcohol rubbed on the skin cause alcohol levels to rise when doing a venipuncture?
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