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No, pit scorpions do not exist. It is part of the betrayal of Luke Castellan, who summons it from the ground. They are fiction. According the the Percy Jackson Wiki, they are a scorpion-like monster, and many were summoned from Tartarus in the First Titan war. According to the Guiness Book of World Records, the most deadly scorpion is the Deathstalker Scorpion; and according to wikipedia, that will not usually kill an adult human, but the pit scorpion can kill in a minute.

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