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Various radioactive isotopes are formed from the fission of uranium, and these have a wide range of half lives, some very long (thousands of years), so will eventually be much safer than when removed from the reactor, but will never completely "decompose" as you put it. Decompose usually means a chemical process-the fuel itself is uranium dioxide so the fission products will also be oxides, there is no other radical in the fuel to form any other chemical compound. Storage must ensure that the waste does not come into contact with water or any other chemical, so I guess it will always remain in oxide form.

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