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Enthalpy of hydration is the energy change for converting 1 mol of an anhydrous substance to 1 mol of the hydrated substance. More the hydration enthalpy more will be the energy released on getting hydrated. The stability of any species is inversely proportional to the energy content and any chemical species tends to becoming more and more stable. Thus having high hydration enthalpy means it will become more stable on hydration and thus it will tend to forming its hydrate.

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