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Iron rusts when it reacts with Oxygen. When iron reacts with oxygen, reddish-brown colored iron-oxides are formed. This is called rust Answer:

Iron can react with oxygen at many rates some cause red iron oxide (rust) others black iron oxides. Rusting is a slow process which is usually regarded as safe unless the rusting iron is essential for mechanical strength in a system. Iron burns in fireworks to create coloured flames. Steel wool (essentially iron fibers) can burn in air causing injury and igniting other materials. Iron burns when heated in an acetylene flame with excess oxygen resulting in molten iron spray. Iron burns violently in a pure oxygen atmosphere.

Aside: When iron "unburns" (rust changes back to iron in a thermite reaction) it can be very dangerous and destructive.

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