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Fission more or less just happens. We can speed it up by increasing neutron flux, and even control the amount of speed-up by controlling the neutron flux using neutron absorbing materials. However, fusion doesn't occur at anything resembling normal conditions on Earth. We've got to produce tremendous temperatures and pressures to overcome the electrostatic repulsion between hydrogen nuclei and get them close enough together for the residual strong force to take over. When they do, it releases a large amount of energy, and it's hard to confine that. Currently the best I'm aware of that we've managed to do while still controlling the reaction is about 65% of input power (that is: for every 100 watts used heating and pressurizing and containing the thing, 65 watts of power were generated) and that only for an instant, but research is continuing and some people think it's possible.

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