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During the explosion of a nova or supernova, the nuclear fusion process fuses lighter elements into heavier ones, which create all the elements heavier than carbon. Iron is one of the elements created.

Iron holds a special place in this process, because it is at the trough of the "packing fraction" curve. When lighter elements like hydrogen fuse into heavier elements like helium, or helium into carbon, energy is released. This is the process that powers the Sun and all the stars. This holds true for all the elements up to iron; energy is released in fusion.

But when iron fuses into anything heavier, energy is ABSORBED in the reaction. So when the nova reaction creates gold, or silver, or uranium or nay heavy element, it's sucking up the energy that the star needs to keep from collapsing. This is what causes the supernova to explode; the star's center is IMPLODING while the outer layers are exploding.

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