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A nice question. When sea water is frozen slowly, the fresh water part freezes first, for it has a higher freezing point. And the salt particles are dissolved into the sea water, making it more saline. For the salt crystal cannot easily fit into the ice crystal matrix.

Thus sea ice is largely fresh water, though there will inevitably be a small contamination by salt.

[An analogous process is used in zone refining of materials where a solid rod of material has a melt zone passed along it by a special heating system. This gradually moves the impurities along to the end of the rod. Once again, the impurities cannot easily fit into the new crystal matrix.]

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