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In the vapor state, beryllium chloride (BeCl₂) exists as a linear molecule with a bond angle of 180°, where the beryllium atom is bonded to two chlorine atoms through covalent bonds. In the solid state, BeCl₂ adopts a polymeric structure, typically forming a three-dimensional network where each beryllium atom is tetrahedrally coordinated by four chloride ions, resulting in a more complex arrangement. This transition from a simple molecular form in the vapor state to a complex lattice in the solid state highlights the differences in bonding and structure due to intermolecular forces.

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