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Because they are the most unreactive gases in the periodic table.

As they are in group 8/0 this means that their outer electron shell is full and therefore makes it extremely difficult to react with other elements, this also means that in order to obtain the gas, you would have to find it pure, which would also be very difficult. Many elements can be obtained by separating it from other elements it has combined with, however this does not apply to the noble gases.

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