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The main intermolecular forces between water molecules are hydrogen bonds which are pretty strong as far as intermolecular forces go. Between hydrocarbon chains (oil) the main intermolecular force are London force which are weaker. For two liquids to be miscible the intermolecular forces between them have to be similar in strength or they won't dissolve. Water and oil have different strengths of intermolecular bonds so don't mix.

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Paul Wyman

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3y ago

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