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In the graphical method using the Gibbs adsorption isotherm equation, the surface excess concentration of AB2 can be obtained by plotting the surface excess Gibbs free energy against the bulk concentration of AB2 at equilibrium. The intercept of the linear plot on the y-axis gives the surface excess concentration of AB2 at the surface. This method helps quantify the extent of the surface concentration of AB2 in the system.

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What is Freundlich adsorption isotherm and Langmuir isotherm?

At a given temperature, the extent of adsorption will increase with the increase of pressure of the gas. The extent of adsorption is measured as x/m, where mi= is the mass of adsorbent and x that of adsorbate. At low pressure, x/m varies linearly with p. As per Freundlich adsorption equation Taking log both sides of the equation, we get, At low pressure, x/m=kP At high pressure, x/m=kPo This is called Freundlich adsorption isotherm at a constant temperature. Freundlich isotherm fails at high pressure and is only for physical adsorption. Langmuir isotherm is represented as x/m=ap/(1+bp) (a and b are constants) At very high pressure,(bp>>1) x/m=a/b At very low pressure,(bp<<1) x/m=ap


How do you calculate concentration of NaCl from absorbance value (only value given)?

To calculate the concentration of NaCl from an absorbance value, you typically use Beer's Law, which states that absorbance (A) is directly proportional to concentration (C). The equation is A = ε * l * C, where ε is the molar absorptivity and l is the path length of the cuvette. By rearranging the equation to solve for concentration, you can use the absorbance value along with known values for ε and l to find the concentration of NaCl. If you have a calibration curve from previous experiments, you can also use it to directly determine concentration from the absorbance value.


Is there a simple equation to calculate the concentration given the absorbance and a time?

You need a graphic concentration versus absorbance.


Are there any synonyms for the words chemical equation?

A chemical equation written in symbols is sometimes called a balance equation, because the numbers of each kind of atom have to balance on both sides. If it's written in words it's called a word equation.


Why can chemists use an acid base titration to determine the concentration of an unknown acid or base?

Chemists can use an acid-base titration to determine the concentration of an unknown acid or base by gradually adding a titrant of known concentration until the reaction reaches the equivalence point, where the amount of titrant equals the amount of substance being analyzed. By measuring the volume of titrant used, they can apply stoichiometric relationships from the balanced chemical equation to calculate the unknown concentration. The use of indicators or pH meters helps identify the endpoint of the titration, ensuring accurate results.

Related Questions

What are the disadvantages of Frenlich adsorption isotherm?

Frenlich adsorption isotherm has no theoretical basis. There are high chances of it failing when the concentration of the adsorbate is high. The equation is, usually, invalid at high pressure.


How can one determine the concentration of hydroxide ions (OH-) from the concentration of hydrogen ions (H)?

To determine the concentration of hydroxide ions (OH-) from the concentration of hydrogen ions (H), you can use the equation for the ion product of water (Kw HOH-). By knowing the concentration of one ion, you can calculate the concentration of the other ion using this equation.


What is the relationship between the Michaelis-Menten equation and the Lineweaver-Burk plot in enzyme kinetics?

The Michaelis-Menten equation describes the relationship between enzyme activity and substrate concentration. The Lineweaver-Burk plot is a graphical representation of the Michaelis-Menten equation, showing the reciprocal of enzyme activity against the reciprocal of substrate concentration. This plot helps determine important parameters like the maximum reaction rate and the Michaelis constant.


How can one determine the concentration of a solution using the equilibrium constant Ka?

To determine the concentration of a solution using the equilibrium constant Ka, you can use the equation Ka products / reactants. By rearranging this equation and plugging in the known values for the equilibrium concentrations of the products and reactants, you can solve for the unknown concentration.


How can one determine the initial concentration of a substance in a chemical reaction?

To determine the initial concentration of a substance in a chemical reaction, you can use the formula: initial concentration (final concentration) / (reaction coefficient). This involves knowing the final concentration of the substance and the reaction coefficient from the balanced chemical equation.


How to use stoichiometry determine the concentration of a substance?

To use stoichiometry to determine the concentration of a substance, you need to first balance the chemical equation for the reaction involving the substance. Next, determine the moles of the known substance and use the balanced equation to relate it to the moles of the unknown substance. Finally, calculate the concentration of the unknown substance in terms of moles per liter based on the volume of the solution.


How can one determine the equilibrium concentration using the equilibrium constant, Kc?

To determine the equilibrium concentration using the equilibrium constant, Kc, you can set up an expression that relates the concentrations of the reactants and products at equilibrium. The equilibrium constant, Kc, is calculated by dividing the concentration of the products by the concentration of the reactants, each raised to the power of their respective coefficients in the balanced chemical equation. By rearranging the equation, you can solve for the unknown concentration to find the equilibrium concentration.


What is the equation of dilution?

The equation of dilution is expressed as ( C_1V_1 = C_2V_2 ), where ( C_1 ) is the initial concentration of the solution, ( V_1 ) is the initial volume, ( C_2 ) is the final concentration after dilution, and ( V_2 ) is the final volume after dilution. This equation is used to determine how to dilute a concentrated solution to achieve a desired concentration. By rearranging the equation, one can solve for any of the variables if the others are known.


What are the advantages of solving a graphical equation algebraically?

You get the exact solution.


How do you calculate KL in langmuir isotherm?

To calculate the Langmuir constant (KL) in the Langmuir isotherm model, you typically perform a nonlinear regression analysis on experimental data using the Langmuir equation: (q = \frac{{q_{max} K_L C}}{{1 + K_L C}}), where q is the adsorption capacity at a given concentration C, and (q_{max}) is the maximum adsorption capacity. The Langmuir constant (KL) can be determined by fitting the experimental data to this equation and solving for KL.


What information is necessary to determine the pH of a solution when you given hydroxide ion concentration?

To determine the pH of a solution from the hydroxide ion concentration, you also need the concentration of the hydrogen ion. Once you have that information, you can use the equation pH = 14 - pOH, where pOH is calculated as -log[OH-] and [OH-] is the hydroxide ion concentration.


What is the concentration of the base (NaOH) in the following titration?

To determine the concentration of the base (NaOH) in a titration, you would use the volume of the base added and the volume and concentration of the acid (typically HCl). By using the balanced chemical equation and the volume and concentration of the acid, you can calculate the concentration of the base.